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Post-UTME Chemistry 2005 Objective — Question 27

Question 27 of 27 from the Post-UTME Screening (Post-UTME) Chemistry 2005 Objective paper, with the correct answer and a full explanation.

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The preferential discharge of sodium during the electrolysis of brine using mercury as cathode is due to one of the following

  • A. High concentration of Na
  • B. Na is lower than H in the electrochemical series
  • C. Discharge of sodium as the amalgam requires less energyCorrect
  • D. Concentration of H+ is higher

Explanation

Mercury forms a sodium amalgam, which significantly lowers the energy required to discharge sodium at the cathode compared to hydrogen.

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