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WAEC Chemistry 2015 Theory — Question 25

Question 25 of 49 from the West African Examinations Council (WAEC) Chemistry 2015 Theory paper, with the correct answer and a full explanation.

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3(b). A saturated organic compound A containing two carbon atoms reacted with ethanoic acid in the presence of a mineral acid to form a compound B with a sweet smell. (i) Name the functional group present in A. (ii) Draw the structure of A. (iii) Write a chemical equation to show the formation of B. (iv) Name the compound B.

Model answer

(i) The functional group present in A is the hydroxyl group (–OH), since A is an alkanol (ethanol) that reacts with an acid to form a sweet-smelling ester. (ii) The structure of A (ethanol, C₂H₅OH) is: H–C(H)(H)–C(H)(H)–OH (i.e. CH₃CH₂OH). (iii) CH₃CH₂OH(l) + CH₃COOH(l) → CH₃COOCH₂CH₃(l) + H₂O(l). (iv) Compound B is ethylethanoate (an ester with a sweet smell).

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