WAEC Chemistry 2020 Theory — Question 2
Question 2 of 6 from the West African Examinations Council (WAEC) Chemistry 2020 Theory paper, with the correct answer and a full explanation.
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2(a) Consider the following compounds: A [H,Cl / C=C / H,Cl arranged trans] B [H,Cl / C=C / Cl,H arranged cis]. (i) What is the relationship between the compounds labelled A and B? (ii) Name each of compounds A and B. (iii) Will the chemical properties of compounds A and B be the same? (iv) Give the reason for the answer stated in 2(a)(iii). (b)(i) Give two characteristic features of boiling. (ii) What would be the effect of each of the following conditions on the boiling point of water? I. The addition of crystals of sodium chloride; II. Reduction of the atmospheric pressure. (c)(i) Differentiate between a saturated and an unsaturated solution. (ii) State two ways by which a saturated solution could be made to dissolve more solute. (iii) State one factor that could affect the solubility of a solid in a liquid.
Model answer
(a)(i) Compounds A and B are geometric isomers. (ii) A is trans-1,2-dichloroethene; B is cis-1,2-dichloroethene. (iii) Yes, A and B will have the same chemical properties. (iv) This is because the compounds have the same functional group. (b)(i) Characteristic features of boiling: Boiling occurs throughout the body of a liquid; It occurs at a definite temperature, known as the boiling point of the liquid. (ii) I. The addition of crystals of sodium chloride (or any other impurity) will cause an increase in the boiling point of water. II. Reduction of the atmospheric pressure causes a decrease in the boiling point of water. (c)(i) Boiling occurs at a fixed temperature (known as the boiling point of the liquid), while evaporation occurs at all temperatures. A saturated solution contains the maximum amount of solute it can hold at that temperature (in the presence of undissolved solute), while an unsaturated solution contains less than the amount of solute it can hold at that temperature. (ii) Ways to make a saturated solution dissolve more solute: Increasing the temperature; Increasing the volume of the solvent. (iii) Factors that could affect the solubility of a solid in a liquid: Nature of the solute; Nature of the solvent; Temperature.
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