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WAEC Chemistry 2018 Theory — Question 16

Question 16 of 24 from the West African Examinations Council (WAEC) Chemistry 2018 Theory paper, with the correct answer and a full explanation.

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3.(b)(i) Define the term enthalpy of neutralization. (ii) Describe briefly how the enthalpy of the reaction of dilute hydrochloric acid and aqueous potassium hydroxide could be determined.

Model answer

(i) Enthalpy of neutralization is the heat released when one mole of H⁺ ions from an acid reacts with one mole of OH⁻ ions from a base to form one mole of water. (ii) Measure known volumes and concentrations of KOH and HCl separately and note their average initial temperature. Mix them in a calorimeter and record the maximum temperature reached. Using the temperature change, the mass (density ≈ 1gcm⁻³) and the specific heat capacity of water, the heat evolved (and hence the enthalpy of neutralization) can be calculated.

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